Melemium Hydrogensulfate H3C6N7(NH2)3(HSO4)3 - the First Triple Protonation of Melem
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The cations and anions of the title salt, 3C(6)H(16)N(+)·HSO(4) (-)·SO(4) (2-), are linked by N-H⋯O and O-H⋯O hydrogen bonds into a three-dimensional network. The hydrogensulfate ion, with a single S-O(H) bond of 1.563 (2) Å, forms a short O-H⋯O hydrogen bond [O⋯O = 2.609 (2) Å] to the sulfate ion. The hydrogensulfate ion accepts two hydrogen bonds from two cations, whereas the sulfate ion, as ...
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ژورنال
عنوان ژورنال: Zeitschrift für anorganische und allgemeine Chemie
سال: 2010
ISSN: 0044-2313
DOI: 10.1002/zaac.201000246